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Cyclopentadienyliron dicarbonyl iodide
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Cyclopentadienyliron dicarbonyl iodide : ウィキペディア英語版
Cyclopentadienyliron dicarbonyl iodide

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Cyclopentadienyliron dicarbonyl iodide is an organoiron compound with the formula (C5H5)Fe(CO)2I. It is a dark brown solid that is soluble in common organic solvents. (C5H5)Fe(CO)2I, or FpI as it is often known, is an intermediate for the preparation of other organoiron compounds such as in ferraboranes.
==Preparation==
Cyclopentadienyliron dicarbonyl iodide is synthesized by the reaction of cyclopentadienyliron dicarbonyl dimer with I2:〔King, R. B.; Stone, F. G. A "Cyclopentadienyl Metal Carbonyls and some Derivatives" Inorg. Syn. 1963, volume 7, pp. 99-115. 〕
:Cp2Fe2(CO)4 + I2 → 2 CpFe(CO)2I
It was first reported by Paulson and Hallam.〔B. F. Hallam, P. L. Paulson "Ferrocene Derivatives. Part III. Cyclopentadienyliron Carbonyls" J. Chem. Soc. 1956, pp. 3031-3037.〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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